
It is summer in San Francisco. The street cars are clanging, the tourists are freezing, and the fog horns are blowing. Another sure sign of summer in San Francisco is surfactant staining on exterior paint projects. The weather conditions in San Francisco represent a laboratory like setting for surfactant staining to occur. Surfactants are soap like ingredients intentionally formulated into latex (water-based) paints. These surfactants act as coalescing agents, and generally help keep what is essentially an emulsion, in suspension. We forget that acrylic resin is a petrochemical byproduct and as such does not mix with water easily.
The presence of surfactants in latex paints normally poses no problem at all. Gradually these surfactants are released by the coating and disappear into the air without anybody noticing. What happens under adverse weather conditions is that a large amount of the surfactants are drawn to the surface rapidly giving the appearance of a sticky Coca-Cola like substance. Surfactants are drawn to moisture (that is their job) and are as such “hydrophilic.” Since these surfactants would have left the coating eventually anyway, their rapid appearance here does not indicate a paint failure in any way, other than in appearance. The remedy when this happens is to simply leave it alone and let it weather off naturally from the rain, or give it a slight rinse with a garden hose, (you will see the surfactants bubble up like soap suds). The worst thing you can do in this situation is to apply more paint which only results in more surfactants being applied to the already surfactant laden surface. Patience is required. I have seen many of these situations through the years and with only a few exeptions they have all resolved themselves with time. In rare cases the staining left from the surfactants eventually had to be reprimed and repainted.
To prevent the problem in the first place it is best to paint early in the day, so as to give the paint film adequate time to form before it is re-introduced to heavy dew or moisture. The unpredictablitity of fog in San Francisco (other than that we know it will surely come sooner or later) makes a painter’s life hell. The only truly safe bet is to paint on days when the fog is non-existent and not expected back soon. This makes for a short painting season!
The same type of problem can be observed in bathrooms painted with latex paint. Here sometimes the only remedy is to paint with oil based paints which by definition have no surfactants in them.
All in all this is a sticky subject that leaves a lot of painters and homeowners puzzled. The one thing I hear over and over again is, “I’ve been painting in San Francisco for 25 years and I have never had this problem before.” To that I can only answer, you have been exceedingly lucky, have you bought a lottery ticket lately?